Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials.

نویسندگان

  • Thibault Cantat
  • Brian L Scott
  • Jaqueline L Kiplinger
چکیده

Anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2), and ThCl(4)(THF)(3.5) have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(iv) halide, alkoxide, amide and organometallic compounds.

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عنوان ژورنال:
  • Chemical communications

دوره 46 6  شماره 

صفحات  -

تاریخ انتشار 2010